Naphtol Oligomers and their Electroconductive Compositions

Abstract By oxidative polycondensation reaction of 1- and 2-naphthols, the polyfunctional polyconjugated soluble and meltable oligomers showing the thermostable, semiconductive and paramagnetic properties, as well as high reactivity in the reactions characteristic for aromatic hydroxyl groups have been obtained.

They have been used as active fillers in preparation of electroconductive compositions on the basis of thermoplasts and rubbers. The antistatic polymer-oligomer compositions of LDPE, PP and PS with naphthol oligomers have been obtained. It has been shown that in partial substitution of carbon black by naphthol oligomers in the composition of vulcanizate from BR, the obtained rubbers exhibit high heat-physical, physical-mechanical and electrical properties.

Keywords electroactive polymers, electroconductive compositions, naphtol, oligonaphtol, oxidation, polycondensation.

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